NK3801 암모늄 니켈(II) 황산염 육수화물 (CAS No. 7785-20-8)

SECTION 1. IDENTIFICATION

Product Name: Ammonium Nickel(II) Sulfate Hexahydrate

CAS #: 7785-20-8

Relevant identified uses of the substance: Scientific research and development

Supplier details:

Stanford Advanced Materials

E-mail: sales@samaterials.com

Tel: (949) 407-8904

Address: 23661 Birtcher Dr., Lake Forest, CA 92630 U.S.A.

SECTION 2. HAZARDS IDENTIFICATION

Classification of the substance or mixture

GHS Classification in accordance with 29 CFR 1910 (OSHA HCS)

Acute toxicity, Oral(Category 4), H302

Acute toxicity, Inhalation(Category 4), H332

Respiratory sensitisation(Category 1), H334

Skin sensitisation(Category 1), H317

Germ cell mutagenicity(Category 2), H341

Carcinogenicity(Category 1A), H350

Reproductive toxicity(Category 1B), H360

Specific target organ toxicity -repeated exposure(Category 1), H372

Acute aquatic toxicity(Category 1), H400

Chronic aquatic toxicity(Category 1), H410

GHS Label elements, including precautionary statements

Pictogram

Signal word

DangerHazard statement(s)

H302 + H332

Harmful if swallowed or if inhaled

H317

May cause an allergic skin reaction.

H334

May cause allergy or asthma symptoms or breathing difficulties if inhaled.

H341

Suspected of causing genetic defects.

H350

May cause cancer.

H360

May damage fertility or the unborn child.

H372

Causes damage to organs through prolonged or repeated exposure.

H410

Very toxic to aquatic life with long lasting effects.

Precautionary statement(s)

P201

Obtain special instructions before use.

P202

Do not handle until all safety precautions have been read and understood.

P260

Do not breathe dust/ fume/ gas/ mist/ Vapors/ spray.

P264

Wash skin thoroughly after handling.

P270

Do not eat, drink or smoke when using this product.

P271

Use only outdoors or in a well-ventilated area.

P272

Contaminated work clothing should not be allowed out of the workplace.

P273

Avoid release to the environment.

P280

Wear protective gloves/ protective clothing/ eye protection/ face protection.

P285

In case of inadequate ventilation wear respiratory protection.

P301 + P312 + P330

IF SWALLOWED: Call a POISON CENTER or doctor/ physician if you feel unwell. Rinse mouth.

P302 + P352

IF ON SKIN: Wash with plenty of soap and water.

P304 + P340 + P312

IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON

CENTER or doctor/ physician if you feel unwell.

P308 + P313

IF exposed or concerned: Get medical advice/ attention.

P333 + P313

If skin irritation or rash occurs: Get medical advice/ attention.

P363

Wash contaminated clothing before reuse.

P391

Collect spillage.

P405

Store locked up.P501

Dispose of contents/ container to an approved waste disposal plant.

Hazards not otherwise classified (HNOC) or not covered by GHS-none

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Substances

Synonyms:Nickel ammonium sulfate

Formula: H8N2NiO8S26H2O

Molecular weight: 394.99 g/mol

CAS-No.: 7785-20-8

EC-No.: 239-793-5

Index-No.: 028-017-00-9

SECTION 4. FIRST AID MEASURES

Description of first aid measures

General advice

Consult a physician. Show this safety data sheet to the doctor in attendance.

Move out of dangerous area.

If inhaled

If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a

physician.

In case of skin contact

Wash off with soap and plenty of water. Take victim immediately to hospital. Consult a physician.

In case of eye contact

Flush eyes with water as a precaution.

If swallowed

Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

Most important symptoms and effects, both acute and delayed

The most important known symptoms and effects are described in the labelling (see section 2) and/or

in section 11

Indication of any immediate medical attention and special treatment needed

No data available

SECTION 5. FIREFIGHTING MEASURES

Extinguishing media

Suitable extinguishing media

Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

Special hazards arising from the substance or mixture

Nitrogen oxides (NOx), Sulphur oxides, Nickel/nickel oxides

Advice for firefighters

Wear self-contained breathing apparatus for firefighting if necessary.

Further information

No data available

SECTION 6. ACCIDENTAL RELEASE MEASURES

Personal precautions, protective equipment and emergency procedures

Use personal protective equipment. Avoid dust formation. Avoid breathing Vapors, mist or gas. Ensure

adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.

For personal protection see section 8.

Environmental precautions

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the

environment must be avoided.

Methods and materials for containment and cleaning up

Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed

containers for disposal.

Reference to other sections

For disposal see section 13.

SECTION 7. HANDLING AND STORAGE

Precautions for safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols.

Provide appropriate exhaust ventilation at places where dust is formed.

For precautions see section 2.

Conditions for safe storage, including any incompatibilities

Keep container tightly closed in a dry and well-ventilated place.

Specific end use(s)

Apart from the uses mentioned in section 1 no other specific uses are stipulated

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Exposure controls

Appropriate engineering controls

Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks

and at the end of workday.

Personal protective equipment

Eye/face protection

Face shield and safety glasses Use equipment for eye protection tested and approved under

appropriate government standards such as NIOSH (US) or EN 166(EU).

Skin protection

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal

technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of

contaminated gloves after use in accordance with applicable laws and good laboratory practices.

Wash and dry hands.

Body Protection

Complete suit protecting against chemicals, The type of protective equipment must be selected

according to the concentration and amount of the dangerous substance at the specific workplace.

Respiratory protection

Where risk assessment shows air-purifying respirators are appropriate use a full-face particle

respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering

controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use

respirators and components tested and approved under appropriate government standards such as

NIOSH (US) or CEN (EU).

Control of environmental exposure

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into theenvironment must be avoided.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Information on basic physical and chemical properties

Appearance

Form: Crystals with lumps

Color: green

Odor

No data available

Odor Threshold

No data available

pH

No data available

Melting point/freezing point

Melting point/range: 85 -89 °C (185 -192 °F)-lit.

Initial boiling point and boiling range

No data available

Flash point

N/A

Evaporation rate

No data available

Flammability (solid, gas)

No data available

Upper/lower flammability or explosive limits

No data available

Vapor pressure

No data available

Vapor density

No data available

Relative density

No data available

Water solubility

No data available

Partition coefficient: n-octanol/water

No data available

Auto-ignition temperature

No data available

Decomposition temperature

No data available

Viscosity

No data available

Explosive properties

No data available

Oxidizing properties

No data available

Other safety information

No data available

SECTION 10. STABILITY AND REACTIVITYReactivity

No data available

Chemical stability

Stable under recommended storage conditions.

Possibility of hazardous reactions

No data available

Conditions to avoid

No data available

Incompatible materials

Strong oxidizing agents

Hazardous decomposition products

Other decomposition products-No data available

In the event of fire: see section 5

SECTION 11. TOXICOLOGICAL INFORMATION

Information on toxicological effects

Acute toxicity

LD50 Oral-Rat-399 mg/kg

Remarks:

Behavioral:Somnolence (general depressed activity). Gastrointestinal:Changes in structure or function

of salivary glands. Diarrhoea

Inhalation: No data available

Dermal: No data available

No data available

Skin corrosion/irritation

No data available

Serious eye damage/eye irritation

No data available

Respiratory or skin sensitisation

Germ cell mutagenicity

In vitro tests showed mutagenic effects

Carcinogenicity

Human carcinogen.

IARC:

1-Group 1: Carcinogenic to humans(Diammonium nickel bis(sulphate) hexahydrate)

ACGIH:

No component of this product present at levels greater than or equal to 0.1% is identified as a

carcinogen or potential carcinogen by ACGIH.

NTP:

Known to be human carcinogen(Diammonium nickel bis(sulphate) hexahydrate)

OSHA:

No component of this product present at levels greater than or equal to 0.1% is identified as a

carcinogen or potential carcinogen by OSHA.

Reproductive toxicity

No data available

Presumed human reproductive toxicant

Specific target organ toxicity -single exposure

No data available

Specific target organ toxicity -repeated exposure

Causes damage to organs through prolonged or repeated exposure.

Aspiration hazard

No data availableAdditional Information

RTECS: WS6061000

To the best of our knowledge, the chemical, physical, and toxicological properties have not been

thoroughly investigated.

Stomach-Irregularities-Based on Human Evidence

Stomach-Irregularities-Based on Human Evidence

SECTION 12. ECOLOGICAL INFORMATION

Toxicity

No data available

Persistence and degradability

No data available

Bioaccumulative potential

No data available

Mobility in soil

No data available

Results of PBT and vPvB assessment

PBT/vPvB assessment not available as chemical safety assessment not required/not conducted

Other adverse effects

An environmental hazard cannot be excluded in the event of unprofessional handling or disposal.

Very toxic to aquatic life with long lasting effects.

SECTION 13. DISPOSAL CONSIDERATIONS

Waste treatment methods

Product

Offer surplus and non-recyclable solutions to a licensed disposal company.

Contact a licensed professional waste disposal service to dispose of this material.

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped

with an afterburner and scrubber.

Contaminated packaging

Dispose of as unused product.

SECTION 14. TRANSPORT INFORMATION

DOT (US)

UN number: 3077

Class: 9

Packing group: III

Proper shipping name:

Environmentally hazardous substances, solid, n.o.s.(Diammonium nickel bis(sulphate)

hexahydrate)

Reportable Quantity

(RQ): 100 lbs

Poison Inhalation Hazard: No

IMDG

Not dangerous goods

IATANot dangerous goods

SECTION 15. REGULATORY INFORMATION

SARA 302 Components

No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.

SARA 313 Components

The following components are subject to reporting levels established by SARA Title III, Section 313:

Diammonium nickel bis(sulphate) hexahydrate

CAS-No.

7785-20-8

Revision Date

1993-04-24

SARA 311/312 Hazards

Acute Health Hazard, Chronic Health Hazard

Massachusetts Right To Know Components

Diammonium nickel bis(sulphate) hexahydrate

CAS-No.

7785-20-8

Revision Date

1993-04-24

Pennsylvania Right To Know Components

Diammonium nickel bis(sulphate) hexahydrate

CAS-No.

7785-20-8

Revision Date

1993-04-24

New Jersey Right To Know Components

Diammonium nickel bis(sulphate) hexahydrate

CAS-No.

7785-20-8

Revision Date

1993-04-24

California Prop. 65 Components

WARNING! This product contains a chemical known to the State of California to cause cancer.

Diammonium nickel bis(sulphate) hexahydrate

CAS-No.

7785-20-8

Revision Date

2007-09-28

SECTION 16. OTHER INFORMATION

Safety Data Sheet according to Regulation (EC) No. 1907/2006 (REACH). The above information is

believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The

information in this document is based on the present state of our knowledge and is applicable to the

product with regard to appropriate safety precautions. It does not represent any guarantee of the

properties of the product.