Cerium-Zirconium-Yttrium Catalyst Description
The Cerium-Zirconium-Yttrium
Catalyst (58.5CeO₂-33.5Zr(Hf) O₂-8Y₂O₃) is a high-performance mixed oxide
catalyst that combines the unique properties of cerium, zirconium, and yttrium
to optimize catalytic efficiency and durability, especially in high-temperature
environments.
Cerium oxide (CeO₂) plays a
critical role in the catalyst’s excellent oxygen storage capacity (OSC),
enabling dynamic oxygen release and uptake through reversible Ce⁴⁺/Ce³⁺ redox
cycles. This feature is essential in automotive and industrial emission
control, where rapid changes in air-to-fuel ratios occur. The redox cycling
capability also supports efficient pollutant conversion and ensures the
catalyst remains active over long operational periods.
Zirconium oxide (ZrO₂), often
stabilized with hafnium, enhances the catalyst’s thermal stability and prevents
sintering, which is crucial for maintaining the active surface area at high
temperatures. The zirconium component helps resist phase transitions that can
degrade catalytic performance, ensuring consistent activity during long-term
use.
Yttrium oxide (Y₂O₃) contributes to
the overall phase stability of the catalyst, helping to maintain the integrity
of the crystal structure during repeated redox cycles. Additionally, yttrium
improves resistance to thermal shock and increases the mechanical strength of
the catalyst material. Together, these elements create a highly durable and
efficient catalyst, making it ideal for use in automotive catalytic converters,
fuel reforming, and industrial gas treatment applications. The synergy between
cerium, zirconium, and yttrium ensures this catalyst provides long-lasting
performance under demanding operational conditions.
Cerium-Zirconium-Yttrium Catalyst Applications
1. Automotive Catalytic Converters: This catalyst is widely
used in automotive emission control systems to reduce harmful pollutants like
carbon monoxide (CO), nitrogen oxides (NOₓ), and hydrocarbons (HC). Its oxygen
storage capacity and redox cycling ability are crucial for the efficient
operation of three-way catalytic converters, ensuring effective pollutant
reduction under fluctuating air-fuel ratios.
2. Gasoline and Diesel Particulate Filters (GPFs and DOCs):
It aids in the oxidation of soot particles and reduces emissions in both
gasoline and diesel engine exhaust systems. Its high thermal stability ensures
the catalyst remains active across a wide range of engine temperatures.
3. Industrial Emission Control: Used in industrial catalytic
processes for reducing volatile organic compounds (VOCs), carbon monoxide (CO),
and other harmful gases in power plants, refineries, and chemical manufacturing
facilities. It provides long-lasting performance in harsh industrial
environments.
4. Fuel Reforming: Employed in steam reforming and partial
oxidation processes for hydrogen production. The catalyst’s ability to handle
high temperatures and provide stable redox properties makes it ideal for
hydrogen production in fuel cells and energy systems.
5. Solid Oxide Fuel Cells (SOFCs): The catalyst’s excellent
ionic conductivity and phase stability make it suitable for use in buffer
layers or support materials in SOFCs, where it aids in the efficient generation
of electricity from hydrogen or other fuels.
6. Oxygen and Gas Sensors: Used in oxygen sensing
applications where rapid and reversible oxygen exchange is necessary for
real-time detection and monitoring of gases, particularly in automotive and
industrial systems.
Cerium-Zirconium-Yttrium Catalyst Packaging
Our products are packaged in customized cartons of various
sizes based on the material dimensions. Small items are securely packed in PP
boxes, while larger items are placed in custom wooden crates. We ensure strict
adherence to packaging customization and the use of appropriate cushioning
materials to provide optimal protection during transportation.

Packaging: Carton, Wooden Box, or Customized.
Kindly review the packaging
details provided for your reference.
Manufacturing Process
1. Testing Method
(1) Chemical Composition Analysis - Verified using techniques
such as GDMS or XRF to ensure compliance with purity requirements.
(2) Mechanical Properties Testing - Includes tensile strength,
yield strength, and elongation tests to assess material performance.
(3) Dimensional Inspection - Measures thickness, width, and
length to ensure adherence to specified tolerances.
(4) Surface Quality Inspection - Checks for defects such as
scratches, cracks, or inclusions through visual and ultrasonic examination.
(5) Hardness Testing - Determines material hardness to confirm
uniformity and mechanical reliability.
Please refer to the SAM testing procedures for detailed information.
Cerium-Zirconium-Yttrium Catalyst FAQs
Q1. What is Cerium-Zirconium-Yttrium Catalyst used for?
This catalyst is primarily used in automotive catalytic
converters, emission control systems, fuel reforming processes, solid oxide
fuel cells (SOFCs), and industrial gas treatment due to its excellent redox
properties, oxygen storage capacity, and thermal stability.
Q2. What makes this catalyst effective in automotive
applications?
The catalyst’s ability to store and release oxygen
efficiently through redox cycles allows it to maintain optimal air-fuel ratios
during lean and rich cycles in three-way catalytic converters, helping reduce
harmful emissions like CO, NOₓ, and hydrocarbons.
Q3. How does this catalyst improve emission control in
industrial applications?
It reduces volatile organic compounds (VOCs), carbon
monoxide, and other toxic gases in industrial environments. Its resistance to
high temperatures and sintering ensures stable, long-term performance in harsh
conditions.
Performance Comparison Table with Competitive Products
Property/Catalyst
|
Ce-Zr-Y (58.5-33.5-8)
|
Ce-Zr-Y (45-50-5)
|
Ce-Zr-Al (50-45-5)
|
Ce-Zr-Pr (50-45-5)
|
Ce-Zr
|
Composition (wt%)
|
CeO₂:58.5, ZrO₂/HfO₂:33.5, Y₂O₃:8
|
CeO₂:45, ZrO₂:50, Y₂O₃:5
|
CeO₂:50, ZrO₂:45, Al₂O₃:5
|
CeO₂:50, ZrO₂:45, Pr₆O₁₁:5
|
CeO₂:50, ZrO₂:50
|
Oxygen Storage Capacity (OSC, μmol O₂/g)
|
750-900
|
450-550
|
300-400
|
550-700
|
200-350
|
Thermal Stability (°C)
|
1050-1150
|
900-1000
|
800-900
|
950-1050
|
800-950
|
Light-off Temperature T50 (°C)
|
200-220
|
250-270
|
280-300
|
230-250
|
280-320
|
Related Information
1. Common Preparation Methods
The Cerium-Zirconium-Yttrium Catalyst (58.5CeO₂-33.5Zr(Hf)O₂-8Y₂O₃)
is typically synthesized using the co-precipitation method. In this process,
aqueous solutions of cerium nitrate (Ce(NO₃)₃), zirconium salts (such as
zirconium chloride or zirconium nitrate), and yttrium nitrate (Y(NO₃)₃) are
mixed in the desired stoichiometric proportions. A precipitating agent, such as
ammonium hydroxide (NH₄OH) or oxalic acid (H₂C₂O₄), is slowly added to the
solution under constant stirring to induce the formation of mixed hydroxides or
oxalates. The resulting precipitate is aged to improve uniformity and
crystallinity. After aging, the precipitate is filtered, thoroughly washed with
deionized water to remove excess salts and impurities, and then dried at
moderate temperatures (typically between 100°C and 120°C). The dried precursor
is then calcined at a high temperature, usually between 500°C and 800°C, to
convert it into the desired mixed oxide phase. This calcination step promotes
the formation of a homogeneous solid solution, which enhances the catalyst's
surface area, redox properties, and thermal stability. The final product is a
fine powder with excellent oxygen storage capacity and sintering resistance,
making it suitable for catalytic applications, particularly in automotive
emission control and industrial processes.